1-(2,6-二溴-4-硝基苯)-3-(4-硝基苯)-三氮烯与锌的显色反应研究

研究了 1- (2 ,6-二溴 - 4 -硝基苯 ) - 3- (4 -硝基苯 ) -三氮烯 (DBNPNPT)与锌的显色反应。在表面活性剂Triton X- 10 0的存在下 ,p H=9.0— 11.0的 Na2 B4 O7- Na OH介质中 ,DBNPNPT与锌 ( )可生成橙黄色络合物。建立以 5 35 nm为参比波长 ,4 4 0 nm为测定波长的双峰双波长测定法 ,该络合物的表观摩尔吸光系数为 1.34× 10 5L· mol-1· cm-1。对葡萄糖酸锌中的锌直接测定 ,结果令人满意     

Axisymmetric three-dimensional finger solutions in Mullins-Sekerka equation

In this paper, we study the existence problem of axisymmetricthree-dimensional finger solutions of Mullins–Sekerkaequation. The finger solutions are travelling wave solutionswhose finger-shaped interfaces are moving along a certain directionat a constant speed within a cylindrical domain. The existenceof at least one axisymmetric three-dimensional finger solutionis obtained through a fixed-point argument of the Hilbert transformation.     

Ba2RV3O11(R=Y,Gd,La):Eu3+(或Dy3+,Bi3+)的合成及发光性能的研究

本文报导了Eu3+,Dy3+在Ba2RV3O11(R=Y,Gd,La)基质中的光谱性质、Bi3+对Dy3+发射强度的影响及温度对Dy3+发射强度的猝灭情况.研究了被取代离子R3+(R=Y,Gd,La)对基质电行迁移带、Eu3+的红橙比、Dy3+黄蓝比的影响,还给出了Dy3+的浓度猝灭值.     

The structure and distances in Yule recursive trees

Based on uniform recursive trees, we introduce random trees with the factor of time, which are named Yule recursive trees. The structure and the distance between the vertices in Yule recursive trees are investigated in this paper. For arbitrary time t > 0, we first give the probability that a Yule recursive tree Y_t is isomorphic to a given rooted tree γ; and then prove that the asymptotic distribution of ζ_t,m, the number of the branches of size m, is the Poisson distribution with parameter λ = 1/m. Finally, two types of distance between vertices in Yule recursive trees are studied, and some limit theorems for them are established.© 2007 Wiley Periodicals, Inc. Random Struct. Alg., 2007     

New instabilities of free-electron laser with an axial guide magnetic field

In this paper, the unperturbed orbits, their stable conditions and the single-pass gain of a free-electron laser have been treated with a single-particle theory to show the existence of a couple of new instabilities and moreover, to discuss their effects. Numerical analyses reveal that the new instabilities will probably affect the operation of free-electron laser when the guide field increases and get into the vicinity of its stability boundary.     

国产航空有机玻璃在冲击载荷下的热粘弹性力学响应

本文以鸟撞高速飞机风档问题为背景,对国产航空有机玻璃3~#PMMA在从准静载荷的应变率(10~(-4)S~(-1))直到冲击载荷的高应变率(10~3S~(-1))范围,和环境温度从-60℃到+100℃范围内的力学性能进行了系统的实验研究,并建立了相应的非线性热粘弹性本构方程。理论预示与实验结果符合。另外还对3~#PMMA低温及高应变率冲击脆化现象进行了讨论,发现与这一现象相一致,3~#PMMA在高应变率冲击条件下的玻璃化温度有明显的提高。     

Characterization of the SiOT Angle and Cation Effects on 29Si Chemical Shifts Of Zeolites

The quantitative relationships between ²⁹Si chemical shifts and (a) the SiOT (T = Al or Si) angles and (b) the nature of the cations of the alkali forms of zeolites can be account for by the changes of charge density and p electron population of the Si atoms as calculated by the extended Hückel method on cluster models.     

ZnS中Te等电子中心的时间分辨光谱研究

用时间分辨光谱研究了很大的Te组分范围内的ZnS_1-xTe_x（x=00 05—085）合金的发光动力学特性，结果表明：不同形态的Te等电子中心具有不同的辐射复 合寿命，从几个ns到几十个ns的范围内变化，当x＝015左右时，寿命达到最大值（约 40ns）.其物理机理源于不同的Te等电子中心具有不同的局域化特性.当Te组分较小时，等 电子中心从Te₁逐渐演变到Te₂，Te₃或Te₄ 时，相应发光寿命增加，表现出不断增强 的激子发光局域化特性；而当Te组分较大时，Te原子团变得较大，其局域势与基体原子势的 相互作用增强，等电子中心的局域化特性减弱，而基体价带扩展态特征变得明显起来，相应 发光寿命逐渐减小.还研究了激子束缚能随Te组分的变化以及发光强度随温度的变化关系， 所得结果进一步支持了时间分辨光谱研究所得到的结论. 关键词： ZnS 等电子中心 时间分辨光谱 局域态     

Sensing and fluorescence behaviors of complex formation between new lariat crown ethers bearing fluorescence sidearm and metal ions in methanol solution

Fluorescence spectroscopic properties of the complex formation between six new C-pivot16-crown-5 ethers bearing fluorescence side arms and metal ions are studied. Six new C-pivot 16-crown-5 ethers that carry fluorescence side arms were synthesized. The research also included the examination of different fluorescent behavior of the new lariat ethers in the presence of silver and sodium ions (Ag⁺ and Na⁺) in methanol. Because of the good fit of the cavity size of these 16-crown-5 ethers with the Ag⁺ and Na⁺ ions, remarkable change in fluorescent spectra were observed. The results showed that the new lariat crown ethers exhibited enhanced selectivity towards sodium ion, but silver ion show quenching abilities towards the ligands. Cooperative participations of the C-pivot side arm oxygen with the ring oxygen molecules in complexation was also confirmed by the single crystal X-ray crystallography of the complex, (C₂₇H₃₀O₇)·NaClO₄. The freezing of crown ring conformation and the diminishment of the chance of sidearm oscillation that occurred upon complexation with sodium ion are the main causes of fluorescent enhancement. The quenching caused by the addition of silver ion was found to explainable by the photo-induced electron transfer that results in the reduction of silver ions.